A fluid is a material (either a liquid or a gas) that does not have a fixed shape. As a result, there are many important properties of fluids that have implications for studying the ability of trees to transport water.

  1. Fluids can flow. This means that materials that are fluids do not have resistance to shear forces (forces directed in differing directions) and as a result they change shape or deform readily
  2. Fluids exert pressure. The force of pressure is created by collisions of molecules within the fluid with the surface in contact.
    1. Defining m as the mass of a particle and v as its velocity, The magnitude of a force can be represented mathematically using an analysis of momentum (p): p=mv
    2. Impulse (I) is defined as the change in momentum of a system. This change can be further related to the force applied (F) over the time t it was applied: I=Δp=F/Δt
    3. Rearranging this equation, we can define the force applied as F=Δpt
    4. The pressure (P) applied by a fluid is defined as the proportion of the applied force to the area over which it is applied: P=F/A

Why is pressure important? Pressure differentials can result in a tendency of fluids towards pressure equilibrium. This can cause motion.

 

Vapor pressure is the pressure directly above a liquid that is composed of vaporized molecules of that liquid. Liquids exist in an equilibrium between the gas form and the liquid form; this equilibrium is also affected by temperature, so at higher temperatures the vapor pressure of a liquid increases (as the gas form becomes more favorable).

 

The figure illustrates liquid water with the immediate gas phase shown in the center and the surrounding atmosphere on top (not to scale). The difference in water saturation between the water vapor phase and the atmosphere is known as the Vapor Pressure Deficit (VPD). Large VPD drives a tendency for water to evaporate (the equilibrium is driven towards the vapor phase).

Water as a fluid has particular properties that are integral to its predominance in living systems, but which also greatly facilitate its transport in large organisms such as trees. Water is a highly polar molecule, as the highly electronegative oxygen withdraws electron density from the two hydrogen atoms. As a result, water molecules can form electrostatic dipole interactions and hydrogen bonds with polar molecules or other water molecules. As a consequence, we see three important properties of water:

  1. Adhesion: the tendency of water to interact with other materials
  2. Cohesion: the tendency of water to cling to itself
  3. High surface tension

A combination of these properties allows for capillary action (explained in the next tab)

Capillary action is made possible by the cohesion of water to itself as well as the adhesion of water to hydrophilic surfaces. The attraction between water molecules and the walls of the tube creates an upward force. The small diameter of the tube allows for the magnitude of this upward force to be greater than that of the gravitational force. As a result, the net force on the column of water is upwards.

Tubes of larger diameter are unable to accommodate capillary action, as shown in the figure above. Wider columns of water will have a larger mass, resulting in a greater magnitude of gravitational force acting on the column of water. In tandem with this fact, the proportion of surface area of adhesion between the walls and the water is decreased with increased with diameter. The overall result of these two factors is that the gravitational force overpowers the adhesion-mediated upward force, and capillary action is not possible.